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CS-W001157 4
Total: USD 88.00

Fmoc-D-Glu(OtBu)-OH

  • CAS No. 104091-08-9

  • Cat. No. CS-W020643
  • Molecule weight425.47
  • Purity≥98%
  • MDL No.MFCD00077055

*For research and further manufacturing use only, not for direct human use.

Fmoc-D-Glu(OtBu)-OH|CS-W020643

Structure of 104091-08-9

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General Information

  • CAS No. 104091-08-9
  • Cat. No. CS-W020643
  • Purity ≥98%
  • MDL No. MFCD00077055
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₄H₂₇NO₆
  • Molecular Weight 425.47
  • Synonym(s) None
  • SMILES O=C(OC(C)(C)C)CC[C@H](C(O)=O)NC(OCC1C2=C(C3=C1C=CC=C3)C=CC=C2)=O

Description

Ni(COD)(DQ), as shown by the Engle lab, is an air- and thermally stable Ni(0) precatalyst. This 18-electron complex has a unique stability profile allowing for easy reaction setup outside an inert atmosphere. Transformations such as the Suzuki-Miyaura coupling, borylation of aryl halides, and alkene hydroarylation have been demonstrated.

Synthesis

  • Route1
    • null|null
      104091-07-8
    • ~98%
    • In-stock
      Fmoc-D-Glu(OtBu)-OH|CS-W020643
      104091-08-9

    References

    • Journal of Organic Chemistry, , vol. 51, # 24 p. 4590 - 4594
  • Route2
    • null|null
      28920-43-6
    • In-stock
      H-D-Glu(OtBu)-OH|CS-W015459
      45125-00-6
    • ~72%
    • In-stock
      Fmoc-D-Glu(OtBu)-OH|CS-W020643
      104091-08-9

    References

    • Journal of Organic Chemistry, , vol. 51, # 24 p. 4590 - 4594
  • Route3

    References

    • Journal of Organic Chemistry, , vol. 51, # 24 p. 4590 - 4594

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   101.93
  • LogP   4.1002
  • H_Acceptors   5
  • H_Donors   2
  • Rotatable_Bonds   7

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