Tris(dibenzylideneacetone)platinum(0)

CAS No. 11072-92-7
Cat. No. CS-0111349
Molecule weight897.96
Purity≥95%
MDL No.MFCD22666053

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Tris(dibenzylideneacetone)platinum(0)|CS-0111349

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General Information

CAS No. 11072-92-7
Cat. No. CS-0111349
Purity ≥95%
MDL No. MFCD22666053
Storage -20°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅₁H₄₂O₃Pt
Molecular Weight 897.96
Synonym(s) None
SMILES O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.O=C(/C=C/C3=CC=CC=C3)/C=C/C4=CC=CC=C4.O=C(/C=C/C5=CC=CC=C5)/C=C/C6=CC=CC=C6.C[Pt](C)(C)(C)(C)C

Description

Tris(dibenzylideneacetone)platinum(0) delivers a stable, air-tolerant source of Pt(0) for catalytic applications. This organoplatinum complex features three dibenzylideneacetone ligands that coordinate platinum in a pseudo-trigonal geometry, enabling efficient incorporation into cross-coupling and C–H activation reactions. The complex exhibits enhanced solubility in aromatic solvents and maintains integrity under standard bench conditions.

Application

Tris(dibenzylideneacetone)platinum(0) serves as a stable, air-tolerant source of Pt(0) for catalytic applications in cross-coupling and C–H activation reactions. Its bench-stable nature facilitates reliable use in palladium-free catalysis, enabling efficient coupling of aryl halides and heteroaryl substrates under mild conditions. The ligand framework provides enhanced solubility and controlled reactivity, supporting scalable synthesis of functionalized biaryls and complex heterocyclic scaffolds.

Safety Information

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Computational Chemistry Data

TPSA 51.21
LogP 15.4472
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 12

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Tris(dibenzylideneacetone)platinum(0)

CAS No. 11072-92-7

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