Lot numbers can be found on the outside label of a product:
1-Bromopyrene
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CAS No. 1714-29-0
- Cat. No. CS-W002101
- Purity≥98%
- MDL No.MFCD00015767
*For research and further manufacturing use only, not for direct human use.
Structure of 1714-29-0
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General Information
- CAS No. 1714-29-0
- Cat. No. CS-W002101
- Purity ≥98%
- MDL No. MFCD00015767
- Storage Store at room temperature
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₆H₉Br
- Molecular Weight 281.15
- Synonym(s) 1-Pyrenyl bromide; 1-Bromopyrene
- SMILES Brc1ccc2c3c1ccc1c3c(cc2)ccc1
Description
1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method.1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons. It may be used in the synthesis of the following:2-methyl-4-pyren-1-yl-but-3-yn-2-ol 1-ethynylpyrenesilsesquioxane (SSQ) based hybridruthenium nanoparticles functionalized with pyrene moietymono- and di-pyrenyl perfluoroalkanesoligo(1-bromopyrene)(OBrP) films dinitropyrene-derived DNA adduct
Synthesis
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Route1
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In-stock
129-00-0 - ~93%
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In-stock
1714-29-0
References
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Hsu, Chung-Yi; Lin, Hung-Yin; Yan, Xuan-You; Huang, Tsung-Syun; Su, Yan-Kuin; Whang, Thou-Jen Journal of the Chinese Chemical Society, 2012 , vol. 59, # 3 p. 289 - 296
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Route2
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110-86-1 -
In-stock
129-00-0
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7726-95-6
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In-stock
1714-29-0
References
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Chemische Berichte, , vol. 70, p. 926,929 FR803820 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 20, p. 1435 US2094227 , ; Justus Liebigs Annalen der Chemie, , vol. 531, p. 1,38
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Route3
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56-23-5
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In-stock
129-00-0
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7726-95-6
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In-stock
1714-29-0
References
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Chemische Berichte, , vol. 70, p. 926,929 FR803820 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 20, p. 1435 US2094227 , ; Justus Liebigs Annalen der Chemie, , vol. 531, p. 1,38
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319-H335
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Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 0
- LogP 5.3465
- H_Acceptors 0
- H_Donors 0
- Rotatable_Bonds 0
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