Lot numbers can be found on the outside label of a product:
Erythromycin A enol ether
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CAS No. 33396-29-1
- Cat. No. CS-0082649
- Purity≥98%
- MDL No.MFCD09840536
*For research and further manufacturing use only, not for direct human use.
Structure of 33396-29-1
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General Information
- CAS No. 33396-29-1
- Cat. No. CS-0082649
- Purity ≥98%
- MDL No. MFCD09840536
- Storage -20°C, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₃₇H₆₅NO₁₂
- Molecular Weight 715.91
- Synonym(s) None
- SMILES C[C@@](OC([C@@H]([C@H]([C@](O)1C)O)C)=C2C)(C2)[C@@H]([C@H]([C@@H]([C@H](C(O[C@@H]1CC)=O)C)O[C@H](O[C@H]3C)C[C@](C)([C@H]3O)OC)C)O[C@H](O[C@@H]4C)[C@@H]([C@H](C4)N(C)C)O
Description
This ligand was developed by the Yu lab to enable the Pd-catalyzed dehydrogenation of aliphatic carboxylic acids through a typically challenging activation of the -methylene C-H bond. This method is chemoselective to carboxylic acids even in the presence of other enolizable functional groups, and may also viably utilize molecular oxygen as the terminal oxidant for the transformation.
Synthesis
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Route1
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In-stock
114-07-8 - ~19%
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105882-69-7 -
In-stock
33396-29-1
References
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Journal of Organic Chemistry, , vol. 52, # 6 p. 990 - 996
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Route2
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In-stock
114-07-8
- ~%
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In-stock
33396-29-1
References
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Kibwage, Isaac O.; Busson, Roger; Janssen, Gerard; Hoogmartens, Jos; Vanderhaeghe, Hubert Journal of Organic Chemistry, 1987 , vol. 52, # 6 p. 990 - 996
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Route3
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105882-69-7
- ~%
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In-stock
33396-29-1
References
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Journal of Organic Chemistry, , vol. 52, # 6 p. 990 - 996
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 165.84
- LogP 2.8923
- H_Acceptors 13
- H_Donors 4
- Rotatable_Bonds 7
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