Tris(pyrazol-1-yl)methane

CAS No. 80510-03-8
Cat. No. CS-0087114
Molecule weight214.23
Purity≥98%
MDL No.MFCD00040255

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General Information

CAS No. 80510-03-8
Cat. No. CS-0087114
Purity ≥98%
MDL No. MFCD00040255
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₀N₆
Molecular Weight 214.23
Synonym(s) Tris(1-pyrazolyl)methane
SMILES N1=CC=CN1C(N2N=CC=C2)N3N=CC=C3

Description

Tris(pyrazol-1-yl)methane delivers a highly symmetric, electron-rich scaffold ideal for coordination chemistry and supramolecular assembly. This bench-stable ligand features three pyrazol-1-yl groups arranged around a central methylene core, enabling strong metal binding and structural predictability in complex architectures.

Application

Tris(pyrazol-1-yl)methane serves as a versatile tridentate ligand in transition metal coordination chemistry, enabling stable complex formation with late transition metals under ambient conditions. Its three pyrazolyl groups provide strong chelation and tunable electronic properties, facilitating applications in catalysis and homogeneous metal complex synthesis. The molecule exhibits good bench stability and ease of purification, making it suitable for iterative synthetic workflows and catalyst development.

Synthesis

Route1
- In-stock
  
  288-13-1
- 67-66-3
- ~78%
- In-stock
  
  80510-03-8
References
- Shakirova; Lavrenova; Kurat'eva; Naumov; Daletskii; Sheludyakova; Logvinenko; Vasilevskii Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2010 , vol. 36, # 4 p. 275 - 283
Route2
- 27258-04-4
- ~30%
- In-stock
  
  288-13-1
- 930-36-9
- In-stock
  
  80510-03-8
References
- Perez, Jorge D.; Yranzo, Gloria I.; Ferraris, Marisa A.; Claramunt, Rosa M.; Lopez, Concepcion; Elguero, Jose Tetrahedron, 1988 , vol. 44, # 20 p. 6429 - 6434
Route3
- 67-66-3
- 288-12-0
- ~%
- In-stock
  
  80510-03-8
References
- Byers, Peter K.; Canty, Allan J.; Honeyman, Thomas Journal of Organometallic Chemistry, 1990 , vol. 385, # 3 p. 417 - 427

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 53.46
LogP 0.8288
H_Acceptors 6
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Catalysts and Ligands Ligands Other Nitrogen Ligands Other Related Nitrogen Ligands

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Nitrogen-Donor Ligands Pyrazole Ligands, Imidazole Ligands, Triazole Ligands

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Tris(pyrazol-1-yl)methane

CAS No. 80510-03-8

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