Methyl 4-methylbenzoate

CAS No. 99-75-2
Cat. No. CS-0008417
Purity≥95%
MDL No.MFCD00008441

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Description

The anaerobic oxidation of methyl p-toluate by cobalt(III) in acetic acid has been investigated.Methyl p-toluate has been employesd as catalyst to investigate the effect of internal/external donor pair in high-yield catalysts for propylene polymerization.

Application

Methyl 4-methylbenzoate serves as a stable, bench-ready building block for aromatic synthesis, enabling efficient derivatization via ester hydrolysis, Suzuki-Miyaura coupling, or electrophilic substitution. Its para-methyl substituent enhances electronic stability and facilitates orthogonal functionalization, while the methyl ester group offers predictable reactivity in standard transformations. Ideal for medicinal chemistry campaigns requiring modular aryl scaffold construction.

General Information

CAS No. 99-75-2
Cat. No. CS-0008417
Purity ≥95%
MDL No. MFCD00008441
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₀O₂
Molecular Weight 150.18
Synonym(s) None
SMILES O=C(OC)C1=CC=C(C)C=C1

Computational Chemistry Data

TPSA 26.3
LogP 1.78162
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315
Precautionary Statements : P264-P280-P302+P352-P362

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

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Methyl 4-methylbenzoate

CAS No. 99-75-2

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