Methyl 5-(chloromethyl)furan-2-carboxylate

CAS No. 2144-37-8
Cat. No. CS-W017480
Purity≥98%
MDL No.MFCD00020922

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Methyl 5-(chloromethyl)furan-2-carboxylate|CS-W017480

Structure of 2144-37-8

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Description

Methyl 5-(chloromethyl)furan-2-carboxylate features a reactive chloromethyl group flanked by a furan ring and ester functionality, enabling direct functionalization in late-stage diversification. This bench-stable reagent integrates readily into synthetic sequences requiring site-specific alkylation or cross-coupling transformations under mild conditions.

Application

Methyl 5-(chloromethyl)furan-2-carboxylate serves as a versatile building block in synthetic organic chemistry, enabling efficient functionalization at the furan C5 position. The chloromethyl group facilitates nucleophilic substitution reactions, while the ester functionality supports downstream transformations such as hydrolysis or reduction. Its bench-stable nature and compatibility with diverse reaction conditions make it valuable for constructing heterocyclic scaffolds and complex molecular architectures in medicinal chemistry and process development workflows.

General Information

CAS No. 2144-37-8
Cat. No. CS-W017480
Purity ≥98%
MDL No. MFCD00020922
Storage -20°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClO₃
Molecular Weight 174.58
Synonym(s) Methyl 5-(chloromethyl)-2-furoate
SMILES COC(=O)C1=CC=C(CCl)O1

Computational Chemistry Data

TPSA 39.44
LogP 1.805
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

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GHS Pictogram :	GHS No : GHS05
Signal Word : Danger	UN#: 1759
Class : 8	Packing Group : Ⅱ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Furan compounds

Key Words

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Methyl 5-(chloromethyl)furan-2-carboxylate

CAS No. 2144-37-8

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