Porphyrin Ligands, Phthalocyanine Ligands
Porphyrin and phthalocyanine ligands are aromatic macrocycles with large planar structures that can coordinate to metal ions through their nitrogen atoms. These ligands are known for their strong absorption of light in the visible and near-infrared regions, making them useful in a variety of optical and electronic applications. Porphyrin-based metal complexes are widely used in solar cells, dye-sensitized solar cells, and luminescent sensors due to their high extinction coefficients and photostability. Phthalocyanine-based metal complexes are used in pigments, photoconductors, and catalysts, where they exhibit excellent chemical stability and thermal resistance. Both porphyrin and phthalocyanine ligands have potential applications in medicine, including as photosensitizers for photodynamic therapy and imaging agents for diagnostic imaging.
Technical Resources
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Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiralChiral chloro-indeno pybox has served as a new ligand for the Yb(OTf)3-catalyzed asymmetric Friedel–Crafts alkylation reaction of indoles with nitroalkenes. The tunable nature of pybox ligands
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2Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral
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3Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral
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4Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral
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5Catalytic asymmetric Friedel–Crafts alkylation of unprotected indoles with nitroalkenes using a novel chiral
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