3,8-Dibromo-1,10-phenanthroline

Name: 3,8-Dibromo-1,10-phenanthroline
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 100125-12-0
Cat. No. CS-W004457
Purity≥95%
MDL No.MFCD09909860

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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3,8-Dibromo-1,10-phenanthroline|CS-W004457

Structure of 100125-12-0

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Description

3,8-Dibromo-1,10-phenanthroline features two bromine substituents at the 3 and 8 positions of the phenanthroline core, enhancing its electron-deficient character and stability. This rigid, planar ligand integrates readily into coordination complexes with transition metals, particularly copper and nickel, enabling robust chelation under standard conditions. The brominated framework improves solubility in organic solvents and facilitates purification via column chromatography. Its steric and electronic profile makes it ideal for catalytic systems requiring controlled metal binding and redox activity.

Application

3,8-Dibromo-1,10-phenanthroline serves as a versatile chelating ligand in transition metal catalysis, particularly in palladium- and copper-mediated cross-coupling reactions. The bromine substituents enhance electronic modulation and provide synthetic handles for further derivatization. Its robust bench stability and high solubility in common organic solvents facilitate straightforward handling and purification, making it well-suited for both academic research and industrial process development.

General Information

CAS No. 100125-12-0
Cat. No. CS-W004457
Purity ≥95%
MDL No. MFCD09909860
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₆Br₂N₂
Molecular Weight 338.00
Synonym(s) 3,8-dibromo-1,7-phenanthroline; 3,8-Dibromo-1,10-phenanthroline
SMILES BrC1=CC2=CC=C3C(N=CC(Br)=C3)=C2N=C1

Computational Chemistry Data

TPSA 25.78
LogP 4.308
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Material Science Material Composite Block Semiconducting Polymer Synthetic Building Block

Material Science Covalent Organic Frameworks Halogenated COFs Linkers

Catalysts and Ligands Ligands Pyridine Ligands Phenanthroline Ligands

Material Science Material Building Blocks Covalent Organic Frameworks (COFs) Linkers Linkers (Others)

Material Science Material Building Blocks Ligands for Functional Metal Complexes Phenanthroline Ligands

Material Science Polymer/Macromolecule Reagents Covalent Organic Frameworks (COFs) Linkers Linkers (Others)

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Phenanthroline Ligands

Key Words

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3,8-Dibromo-1,10-phenanthroline

CAS No. 100125-12-0

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