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CS-W001157 4
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Tetrabutylammonium (acetate) contains 10-15%AcOH

  • CAS No. 10534-59-5

  • Cat. No. CS-W008039
  • Molecule weight301.51
  • Purity98% (contains 10-15%AcOH)
  • MDL No.MFCD00043208

*For research and further manufacturing use only, not for direct human use.

Tetrabutylammonium (acetate) contains 10-15%AcOH|CS-W008039

Structure of 10534-59-5

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General Information

  • CAS No. 10534-59-5
  • Cat. No. CS-W008039
  • Purity 98% (contains 10-15%AcOH)
  • MDL No. MFCD00043208
  • Storage 4°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₈H₃₉NO₂
  • Molecular Weight 301.51
  • Synonym(s) Tetra-n-butylammonium (acetate)
  • SMILES CCCC[N+](CCCC)(CCCC)CCCC.CC([O-])=O

Description

Tetrabutylammonium acetate (TBAA) is a phase transfer catalyst (PTC).Tetrabutylammonium acetate can be used: To catalyze the alkynylation of carbonyl compounds with trimethylsilylacetylenes providing good yields of propargylic alcohols. Along with tetrabutylammonium bromide (TBAB) as a molten reaction medium in the synthesis of 4-aryl-2-quinolones. As a promoter in the regioselective direct arylation of azoles (1-methylpyrazole, oxazole, and thiazole) with aryl bromides in presence of palladium acetate catalyst.As an ionic liquid to dissolve cellulose in the presence of DMSO co-solvent.As an activator in the synthesis of disubstituted alkynes through copper-free Sonogashira coupling reaction.

Synthesis

  • Route1
    • null|null
      2052-49-5
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      64-19-7
    • ~%
    • In-stock
      Tetrabutylammonium (acetate) contains 10-15%AcOH|CS-W008039
      10534-59-5

    References

    • Journal of the American Chemical Society, , vol. 132, p. 1232 - 1233
  • Route2
    • In-stock
      (Diacetoxyiodo)benzene|CS-W011998
      3240-34-4
    • ~%
    • null|null
      26735-53-5
    • In-stock
      Tetrabutylammonium (acetate) contains 10-15%AcOH|CS-W008039
      10534-59-5

    References

    • Organic Letters, , vol. 10, # 20 p. 4413 - 4416
  • Route3
    • null|null
      1112-67-0
    • In-stock
      Potassium acetate, for molecular biology|CS-0911127
      127-08-2
    • ~%
    • In-stock
      Tetrabutylammonium (acetate) contains 10-15%AcOH|CS-W008039
      10534-59-5

    References

    • Angewandte Chemie, International Edition, , vol. 48, # 40 p. 7398 - 7401 Angewandte Chemie, , vol. 121, # 40 p. 7534 - 7537

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   40.13
  • LogP   3.7598
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   12

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