[Ir(ppy)2(bpy)]PF6

Name: [Ir(ppy)2(bpy)]PF6
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CAS No. 106294-60-4
Cat. No. CS-0105686
Purity≥97%
MDL No.MFCD28976160

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 106294-60-4
Cat. No. CS-0105686
Purity ≥97%
MDL No. MFCD28976160
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₂H₂₄F₆IrN₄P
Molecular Weight 801.74
Synonym(s) None
SMILES F[P-](F)(F)(F)(F)F.C1(C2=CC=CC=[N]23)=CC=CC=C1[Ir+]435(C6=CC=CC=C6C7=[N]5C=CC=C7)[N]8=CC=CC=C8C9=[N]4C=CC=C9

Description

This iridium complex features a chelated bipyridine and two phenylpyridine ligands, delivering strong phosphorescence with enhanced charge transport. The hexafluorophosphate counterion improves solubility and facilitates electrochemical stability in solution-processable devices.

Application

(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) hexafluorophosphate serves as a highly efficient phosphorescent iridium complex, enabling strong emission in organic light-emitting diodes (OLEDs). Its robust photoluminescence and stability under operational conditions make it a reliable choice for emissive layer integration. The complex exhibits excellent functional group tolerance and facilitates straightforward device fabrication due to its solubility and thermal resilience.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

TPSA 15.52
LogP 6.1895
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Catalysts and Ligands Catalysts Photocatalysts Iridium Series Photocatalysts

Catalysts and Ligands Catalysts Transition Metal Catalysts Ir Catalysts

Material Science Electronic Materials Organic Light-Emitting Diode (OLED) Materials Light Emitters and Dopants

Catalysis Photocatalysts

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Catalysis C-H Activation Iridium Compounds

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Transition Elements Iridium

Key Words

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[Ir(ppy)2(bpy)]PF6

CAS No. 106294-60-4

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