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CS-W001157 4
Total: USD 88.00

Dodecane

  • CAS No. 112-40-3

  • Cat. No. CS-0152244
  • Purity≥98%
  • MDL No.MFCD00008969

*For research and further manufacturing use only, not for direct human use.

Dodecane|CS-0152244

Structure of 112-40-3

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General Information

  • CAS No. 112-40-3
  • Cat. No. CS-0152244
  • Purity ≥98%
  • MDL No. MFCD00008969
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₂₆
  • Molecular Weight 170.34
  • Synonym(s) Ba 51-090453
  • SMILES CCCCCCCCCCCC

Description

This 2-pyridylsulfinate enables Suzuki-Miyaura cross coupling with aryl halides to access diverse pyridine derivatives as reported by the laboratory of Michael Willis.. No longer impeded by unstable 2-pyridyl boronates, the sulfinate alternatives provide Pd-catalyzed coupling routes to therapeutically valuable pyridine rings.

Synthesis

  • Route1

    References

    • Bajracharya, Gan B.; Nogami, Tsutomu; Jin, Tienan; Matsuda, Kumiko; Gevorgyan, Vladimir; Yamamoto, Yoshinori Synthesis, 2004 , # 2 p. 308 - 311
  • Route2
    • null|null
      106165-36-0
    • ~76%
    • In-stock
      Dodecane|CS-0152244
      112-40-3

    References

    • Sutton, Andrew D.; Waldie, Fraser D.; Wu, Ruilian; Schlaf, Marcel; 'Pete'Silks, Louis A.; Gordon, John C. Nature Chemistry, 2013 , vol. 5, # 5 p. 428 - 432
  • Route3
    • null|null
      13187-99-0
    • ~10%
    • In-stock
      Dodecane|CS-0152244
      112-40-3

    References

    • Nakamura; Yorimitsu; Shinokubo; Oshima Bulletin of the Chemical Society of Japan, 2001 , vol. 74, # 4 p. 747 - 752

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS08
Signal Word : Danger
UN#: 3082
Class : 9
Packing Group : Ⅲ
Hazard Statements : H227-H304
Precautionary Statements : P210-P280-P331-P370+P378-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   4.9272
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   9

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