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CS-W001157 4
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Dipyridin-2-ylmethane

  • CAS No. 1132-37-2

  • Cat. No. CS-0155843
  • Purity≥98%
  • MDL No.MFCD14706789

*For research and further manufacturing use only, not for direct human use.

Dipyridin-2-ylmethane|CS-0155843

Structure of 1132-37-2

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General Information

  • CAS No. 1132-37-2
  • Cat. No. CS-0155843
  • Purity ≥98%
  • MDL No. MFCD14706789
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₁H₁₀N₂
  • Molecular Weight 170.22
  • Synonym(s) None
  • SMILES N=1C=CC=CC1CC2=NC=CC=C2

Description

Dipyridin-2-ylmethane features a rigid, planar backbone with two pyridine rings linked by a methylene bridge, enabling strong chelation to transition metals. This geometry supports coordination in catalytic systems and supramolecular assemblies. The molecule exhibits high thermal stability and solubility in polar organic solvents, facilitating use in synthesis and material design under standard conditions.

Application

Dipyridin-2-ylmethane serves as a versatile bispyridyl ligand in transition metal catalysis, enabling efficient coordination to palladium, nickel, and copper centers. Its rigid, planar architecture facilitates formation of stable chelates in cross-coupling reactions, enhancing catalyst activity and selectivity. The molecule exhibits excellent bench stability and compatibility with diverse functional groups, making it a practical choice for synthetic applications requiring robust ligand performance in standard organic transformations.

Synthesis

  • Route1

    References

    • Andell, Ove; Maaranen, Janne; Hoikka, Jouni; Vanne, Tiina; Rautio, Soile Patent: US2003/225275 A1, 2003 ; Location in patent: Page 16 ;
  • Route2
    • null|null
      109-06-8
    • null|null
      372-48-5
    • ~97%
    • In-stock
      Dipyridin-2-ylmethane|CS-0155843
      1132-37-2

    References

    • Dyker, Gerald; Muth, Oliver European Journal of Organic Chemistry, 2004 , # 21 p. 4319 - 4322
  • Route3
    • null|null
      109-06-8
    • ~%
    • In-stock
      Dipyridin-2-ylmethane|CS-0155843
      1132-37-2

    References

    • Angewandte Chemie - International Edition, , vol. 46, # 15 p. 2643 - 2645

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H320-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   25.78
  • LogP   2.0674
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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