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CS-W001157 4
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5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde

  • CAS No. 118688-53-2

  • Cat. No. CS-0110998
  • Molecule weight390.43
  • Purity≥97%
  • MDL No.MFCD27937712

*For research and further manufacturing use only, not for direct human use.

5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde|CS-0110998

Structure of 118688-53-2

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General Information

  • CAS No. 118688-53-2
  • Cat. No. CS-0110998
  • Purity ≥97%
  • MDL No. MFCD27937712
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₇H₁₈O₃
  • Molecular Weight 390.43
  • Synonym(s) 5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxaldehyde
  • SMILES O=CC1=CC=C(C=C1)C2=CC(C3=CC=C(C=C3)C=O)=CC(C4=CC=C(C=C4)C=O)=C2

Description

5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde features a rigid, electron-rich terphenyl core flanked by formyl groups at both ends, enabling efficient conjugation and directional assembly in π-stacked architectures. This bifunctional aldehyde scaffold facilitates site-specific coupling in supramolecular and materials applications under standard conditions.

Application

5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde serves as a versatile triaryl aldehyde scaffold for constructing complex molecular architectures. Its three orthogonal aldehyde functionalities enable sequential functionalization in multistep syntheses, facilitating the assembly of conjugated systems, dendrimers, and functionalized ligands. The molecule exhibits good bench stability and compatibility with standard carbonyl coupling reactions, including reductive amination and Grignard additions, making it well-suited for modular synthesis in materials science and advanced organic chemistry applications.

Synthesis

  • Route1

    References

    • Synthesis, , # 23 p. 3653 - 3658
  • Route2
    • In-stock
      4,4''-Dibromo-5'-(4-bromophenyl)-1,1':3',1''-terphenyl|CS-W004614
      7511-49-1
    • null|null
      68-12-2
    • ~80%
    • In-stock
      5'-(4-Formylphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarbaldehyde|CS-0110998
      118688-53-2

    References

    • European Journal of Organic Chemistry, , # 12 p. 2422 - 2427
  • Route3

    References

    • Tetrahedron, , vol. 62, # 51 p. 12041 - 12050

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   51.21
  • LogP   6.1251
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   6

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