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CS-W001157 4
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Bis(2-methylallyl)dipalladium dichloride

  • CAS No. 12081-18-4

  • Cat. No. CS-0035161
  • Molecule weight393.94
  • Purity≥98%
  • MDL No.MFCD08561141

*For research and further manufacturing use only, not for direct human use.

Bis(2-methylallyl)dipalladium dichloride|CS-0035161

Structure of 12081-18-4

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General Information

  • CAS No. 12081-18-4
  • Cat. No. CS-0035161
  • Purity ≥98%
  • MDL No. MFCD08561141
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₄Cl₂Pd₂
  • Molecular Weight 393.94
  • Synonym(s) dichloroniopalladium
  • SMILES CC(C)C.CC(C)C.[Pd]1Cl[Pd]Cl1

Description

Bis(2-methylallyl)dipalladium dichloride serves as a robust, bench-stable precursor for palladium-catalyzed cross-coupling reactions. Featuring two 2-methylallyl ligands coordinated to a Pd₂Cl₂ core, it enables efficient C–C and C–heteroatom bond formation under mild conditions. The sterically protected allyl groups enhance reactivity while minimizing decomposition pathways. This complex streamlines catalyst activation in synthetic workflows involving nickel or palladium systems.

Application

Bis(2-methylallyl)dipalladium dichloride serves as a robust, bench-stable precursor for palladium-catalyzed cross-coupling reactions. It enables efficient C–C and C–heteroatom bond formation under mild conditions, demonstrating broad functional group tolerance and compatibility with standard reaction protocols. Its well-defined structure facilitates reproducible catalytic activity in Suzuki-Miyaura, Stille, and Negishi couplings, making it a reliable choice for synthetic chemists constructing complex molecular architectures.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   N/A

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