6-Bromo-2-methoxynicotinonitrile

Name: 6-Bromo-2-methoxynicotinonitrile
Brand: ChemScene
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CAS No. 1256790-45-0
Cat. No. CS-0150532
Purity≥98%
MDL No.MFCD18258525

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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6-Bromo-2-methoxynicotinonitrile|CS-0150532

Structure of 1256790-45-0

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General Information

CAS No. 1256790-45-0
Cat. No. CS-0150532
Purity ≥98%
MDL No. MFCD18258525
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrN₂O
Molecular Weight 213.03
Synonym(s) None
SMILES COC1=C(C=CC(=N1)Br)C#N

Description

6-Bromo-2-methoxynicotinonitrile features a bromine atom at the 6-position and a methoxy group at the 2-position on a nicotinonitrile scaffold, delivering a sterically accessible site for cross-coupling. The electron-deficient pyridine core enhances reactivity in transition-metal-catalyzed transformations. This bench-stable building block enables efficient access to functionalized heterocycles in medicinal chemistry and materials synthesis.

Application

6-Bromo-2-methoxynicotinonitrile serves as a versatile building block in medicinal chemistry and heterocyclic synthesis, enabling efficient access to substituted pyridine scaffolds. Its bromo group facilitates Suzuki-Miyaura and Stille couplings, while the nitrile and methoxy functionalities offer orthogonal handles for further functionalization. The compound exhibits excellent bench stability and is compatible with standard reaction conditions, simplifying purification and scalability in API development workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 45.91
LogP 1.72438
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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6-Bromo-2-methoxynicotinonitrile

CAS No. 1256790-45-0

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