Methyl 4-bromo-5-chloropicolinate

Name: Methyl 4-bromo-5-chloropicolinate
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CAS No. 1256834-36-2
Cat. No. CS-0160801
Purity≥98%
MDL No.MFCD18257373

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 4-bromo-5-chloropicolinate|CS-0160801

Structure of 1256834-36-2

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General Information

CAS No. 1256834-36-2
Cat. No. CS-0160801
Purity ≥98%
MDL No. MFCD18257373
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrClNO₂
Molecular Weight 250.48
Synonym(s) 2-Pyridinecarboxylic acid, 4-bromo-5-chloro-, methyl ester
SMILES O=C(OC)C1=NC=C(Cl)C(Br)=C1

Description

Methyl 4-bromo-5-chloropicolinate features a sterically accessible pyridine core bearing strategically positioned bromo and chloro substituents, enabling selective cross-coupling reactions. This bench-stable derivative integrates readily into synthetic sequences requiring halogen-directed functionalization, offering enhanced reactivity control in transition metal-catalyzed transformations.

Application

Methyl 4-bromo-5-chloropicolinate serves as a versatile building block in synthetic organic chemistry, enabling regioselective cross-coupling reactions via its complementary halogenation pattern. The bromo group facilitates palladium-catalyzed coupling with boronic acids, while the chloro substituent offers orthogonal reactivity for subsequent functionalization. Its bench-stable methyl ester functionality simplifies purification and supports downstream transformations into bioactive heterocycles or pharmaceutical intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 2.2841
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 4-bromo-5-chloropicolinate

CAS No. 1256834-36-2

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