(R)-3,3'-Bis[(10-phenylanthracen-9-yl)]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Name: (R)-3,3'-Bis[(10-phenylanthracen-9-yl)]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
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Availability: InStock
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CAS No. 1262129-47-4
Cat. No. CS-0096657
Purity≥97%
MDL No.None

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(R)-3,3'-Bis[(10-phenylanthracen-9-yl)]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate|CS-0096657

Structure of 1262129-47-4

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Description

This chiral phosphoric acid features a rigid binaphthyl backbone with bulky phenylanthracene substituents that enhance steric shielding and electronic modulation. The (R)-configuration imparts enantioselective recognition capabilities, enabling effective asymmetric catalysis in stereoselective transformations under mild conditions.

Application

(R)-3,3'-Bis[(10-phenylanthracen-9-yl)]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate serves as a sterically demanding, chiral phosphate ligand with enhanced π-stacking and electronic modulation from the anthracene-substituted naphthyl framework. It enables enantioselective transformations in transition-metal catalysis, particularly in asymmetric phosphorylation and C–H functionalization reactions, leveraging its robust bench stability and orthogonal functional group tolerance for streamlined purification and scalable synthesis.

General Information

CAS No. 1262129-47-4
Cat. No. CS-0096657
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆₀H₃₇O₄P
Molecular Weight 852.91
Synonym(s) None
SMILES O=P1(O)OC2=C(C3=C(C=CC=C4)C4=CC(C5=C(C=CC=C6)C6=C(C7=CC=CC=C7)C8=C5C=CC=C8)=C3O1)C9=C(C=CC=C9)C=[C@]2[C@]%10=C(C=CC=C%11)C%11=C(C%12=CC=CC=C%12)C%13=C%10C=CC=C%13

Computational Chemistry Data

TPSA 55.76
LogP 16.8124
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 4

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315
Precautionary Statements : P264-P280-P302+P352-P362

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(R)-3,3'-Bis[(10-phenylanthracen-9-yl)]-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

CAS No. 1262129-47-4

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