Bolm's ligand

Name: Bolm's ligand
Brand: ChemScene
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CAS No. 127049-50-7
Cat. No. CS-0093779
Purity≥97%
MDL No.MFCD32670769

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 127049-50-7

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Description

Bolm's ligand features a sterically hindered, electron-rich phosphine scaffold that enables robust coordination in palladium-catalyzed cross-coupling reactions. This bench-stable ligand enhances reaction efficiency under mild conditions, delivering high yields with broad functional group tolerance and minimal catalyst loading.

Application

Bolm's ligand serves as a robust, bench-stable phosphine catalyst for palladium-catalyzed cross-coupling reactions, enabling efficient C–C and C–heteroatom bond formation under mild conditions. Its electron-rich, sterically tuned structure enhances catalytic activity and functional group tolerance, facilitating reliable coupling in complex molecule synthesis.

General Information

CAS No. 127049-50-7
Cat. No. CS-0093779
Purity ≥97%
MDL No. MFCD32670769
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₀H₂₈N₂O₂
Molecular Weight None
Synonym(s) R,R-α,α'-bis(1,1-diMethylethyl)-[2,2'-Bipyridine]-6,6'-diMethanol
SMILES CC(C)(C)[C@@H](O)C1=CC=CC(C2=NC([C@H](O)C(C)(C)C)=CC=C2)=N1

Computational Chemistry Data

TPSA 66.24
LogP 4.3026
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 3

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Bolm's ligand

CAS No. 127049-50-7

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