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Structure of 13411-42-2
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2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalent.
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GHS Pictogram :
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GHS No : GHS07,GHS08,GHS09
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Signal Word : Warning
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UN#: 3082
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Class : 9
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Packing Group : Ⅲ
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Hazard Statements : H332-H362-H372-H411
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Precautionary Statements : P260-P261-P263-P264-P270-P271-P273-P304+P340-P391-P501
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Lot numbers can be found on the outside label of a product: