(3aR,6aR)-1-Methyloctahydropyrrolo[3,4-b]pyrrole

Name: (3aR,6aR)-1-Methyloctahydropyrrolo[3,4-b]pyrrole
Brand: ChemScene
Availability: InStock
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CAS No. 1353644-77-5
Cat. No. CS-0112643
Purity≥97%
MDL No.MFCD11656776

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(3aR,6aR)-1-Methyloctahydropyrrolo[3,4-b]pyrrole|CS-0112643

Structure of 1353644-77-5

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Description

This bicyclic amine features a rigid, nitrogen-rich scaffold with defined stereochemistry at the 3a and 6a positions, offering enhanced conformational stability. The methyl group at the 1-position provides steric shielding, improving metabolic resistance and solubility in organic media. Ideal for asymmetric synthesis and as a chiral auxiliary in medicinal chemistry applications.

Application

(3aR,6aR)-1-Methyloctahydropyrrolo[3,4-b]pyrrole serves as a stereochemically defined, saturated heterocyclic building block with predictable reactivity in synthetic routes to bioactive molecules. Its rigid, polycyclic framework provides structural diversity and conformational restraint, enabling efficient incorporation into complex scaffolds via standard functionalization protocols. Bench-stable and compatible with diverse reaction conditions, it facilitates the construction of pharmaceutically relevant architectures with high stereoselectivity.

General Information

CAS No. 1353644-77-5
Cat. No. CS-0112643
Purity ≥97%
MDL No. MFCD11656776
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₄N₂
Molecular Weight 126.20
Synonym(s) (3aR,6aR)-1-Methyl-hexahydropyrrolo[3,4-b]pyrrole
SMILES CN1[C@](CNC2)([H])[C@]2([H])CC1

Computational Chemistry Data

TPSA 15.27
LogP -0.0901
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H332-H335
Precautionary Statements : P233-P260-P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P340-P362-P403-P405-P501

Quality Control

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Other Classifications

Building Blocks Skeleton Bridge Rings compounds Other bridge ring compounds

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Key Words

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(3aR,6aR)-1-Methyloctahydropyrrolo[3,4-b]pyrrole

CAS No. 1353644-77-5

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