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Zinc(II) dibutyldithiocarbamate

  • CAS No. 136-23-2

  • Cat. No. CS-0152117
  • Molecule weight474.13
  • Purity≥95%
  • MDL No.MFCD00067274

*For research and further manufacturing use only, not for direct human use.

Zinc(II) dibutyldithiocarbamate|CS-0152117

Structure of 136-23-2

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General Information

  • CAS No. 136-23-2
  • Cat. No. CS-0152117
  • Purity ≥95%
  • MDL No. MFCD00067274
  • Storage 4°C, stored under nitrogen, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₈H₃₆N₂S₄Zn
  • Molecular Weight 474.13
  • Synonym(s) None
  • SMILES CCCCN(CCCC)C(=S)[S-].CCCCN(CCCC)C(=S)[S-].[Zn+2]

Description

Zinc(II) dibutyldithiocarbamate delivers robust chelation through its dithiocarbamate ligands, forming stable complexes under ambient conditions. This moisture-tolerant reagent functions effectively in catalytic systems and as a stabilizer in polymer processing, offering reliable performance without decomposition.

Application

Zinc(II) dibutyldithiocarbamate serves as a stable, bench-ready catalyst for carbon–carbon and carbon–heteroatom bond formations, particularly in Michael additions and cycloadditions. Its well-documented functional group tolerance and ease of handling facilitate efficient reaction setups, while the dithiocarbamate ligand enhances metal coordination stability and promotes recyclability in catalytic cycles.

Synthesis

  • Route1

    References

    • Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, , vol. 46, # 7 p. 1121 - 1124
  • Route2
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      2391-80-2
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      7646-85-7
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    • In-stock
      Zinc(II) dibutyldithiocarbamate|CS-0152117
      136-23-2

    References

    • Souza, Antonio G. de; Souza, Jose H. de; Airoldi, Claudio Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 7 p. 1751 - 1754

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS09
Signal Word : Warning
UN#: 3077
Class : 9
Packing Group : Ⅲ
Hazard Statements : H315-H317-H319-H335-H410
Precautionary Statements : P261-P261-P264-P273-P280-P302+P352-P302+P352

Quality Control

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Computational Chemistry Data

  • TPSA   6.48
  • LogP   5.4383
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   12

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