(R,R,R)-(+)-Ph-SKP

Name: (R,R,R)-(+)-Ph-SKP
Brand: ChemScene
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CAS No. 1360823-43-3
Cat. No. CS-W023184
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 1360823-43-3

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Description

(R,R,R)-(+)-Ph-SKP is a chiral, bench-stable synthon featuring a rigid, electron-rich aryl-substituted scaffold that facilitates stereoselective coupling reactions. This configuration enables precise control in asymmetric synthesis, particularly in the construction of complex biaryl architectures and functionalized heterocycles under mild conditions.

Application

(R,R,R)-(+)-Ph-SKP serves as a chiral auxiliary in asymmetric synthesis, enabling stereoselective transformations through its rigid, well-defined three-dimensional structure. It functions effectively in enolate alkylations and conjugate additions, offering high diastereoselectivity and ease of removal under mild conditions. Its bench-stable nature and compatibility with common reaction protocols make it a practical choice for iterative synthetic sequences in complex molecule construction.

General Information

CAS No. 1360823-43-3
Cat. No. CS-W023184
Purity ≥97%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₄H₃₈O₂P₂
Molecular Weight 660.72
Synonym(s) 1,1'-[(5aR,8aR,14aR)-5a,6,7,8, 8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-diphenyl-Phosphine
SMILES C1(P(C2=CC=CC=C2)C3=CC=CC=C3)=CC=CC4=C1OC5(OC(C(P(C6=CC=CC=C6)C7=CC=CC=C7)=CC=C8)=C8C[C@H]5CCC9)[C@H]9C4

Computational Chemistry Data

TPSA 18.46
LogP 7.8856
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 6

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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(R,R,R)-(+)-Ph-SKP

CAS No. 1360823-43-3

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