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CS-W001157 4
Total: USD 88.00

Methyl 4-(2-bromoethyl)benzoate

  • CAS No. 136333-97-6

  • Cat. No. CS-W022837
  • Purity≥95%
  • MDL No.MFCD14708225
  • HazMat Fee +

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    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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*For research and further manufacturing use only, not for direct human use.

Methyl 4-(2-bromoethyl)benzoate|CS-W022837

Structure of 136333-97-6

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Description

Methyl 4-(2-bromoethyl)benzoate features a bromoethyl chain appended to the para position of a methyl benzoate scaffold. This electrophilic handle enables efficient coupling in nucleophilic substitution reactions, particularly in bioconjugation and polymer functionalization workflows. The compound exhibits stability under standard bench conditions and facilitates site-specific modification in complex molecular architectures.

Application

Methyl 4-(2-bromoethyl)benzoate serves as a versatile building block for C–C and C–heteroatom bond formation, enabling efficient functionalization of aromatic systems. The bromoethyl side chain facilitates nucleophilic substitution reactions with amines, thiols, and azide derivatives, while the ester group remains stable under standard reaction conditions. Its bench-stable nature and compatibility with diverse coupling protocols make it ideal for constructing complex scaffolds in medicinal chemistry and materials synthesis.

General Information

  • CAS No. 136333-97-6
  • Cat. No. CS-W022837
  • Purity ≥95%
  • MDL No. MFCD14708225
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₁BrO₂
  • Molecular Weight 243.10
  • Synonym(s) Benzoic acid, 4-(2-bromoethyl)-, methyl ester
  • SMILES COC(=O)C1=CC=C(CCBr)C=C1

Computational Chemistry Data

  • TPSA   26.3
  • LogP   2.4106
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   3

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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