3-Bromo-4-chlorophenol

Name: 3-Bromo-4-chlorophenol
Brand: ChemScene
Availability: InStock
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CAS No. 13659-24-0
Cat. No. CS-W005264
Purity≥98%
MDL No.MFCD00070740

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 13659-24-0

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Description

3-Bromo-4-chlorophenol features a bromine substituent at the meta position and a chlorine atom at the para position relative to the hydroxyl group, creating a uniquely electron-deficient aromatic scaffold. This configuration enhances its reactivity in cross-coupling processes and facilitates incorporation into functionalized pharmaceutical intermediates. The compound exhibits robust stability under standard handling conditions and demonstrates favorable solubility in common organic solvents, enabling seamless integration into synthetic workflows.

Application

3-Bromo-4-chlorophenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling regioselective functionalization via palladium-catalyzed cross-coupling reactions. Its bromo and chloro substituents offer orthogonal reactivity for sequential transformations, while the phenolic hydroxyl group provides a handle for derivatization or protection. The compound exhibits excellent bench stability and is readily purified by recrystallization or column chromatography, facilitating integration into multi-step synthetic sequences.

General Information

CAS No. 13659-24-0
Cat. No. CS-W005264
Purity ≥98%
MDL No. MFCD00070740
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₄BrClO
Molecular Weight 207.45
Synonym(s) 3-Bromo-4-chlorophenol
SMILES BrC1=C(C=CC(=C1)O)Cl

Computational Chemistry Data

TPSA 20.23
LogP 2.8081
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-4-chlorophenol

CAS No. 13659-24-0

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