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CS-W001157 4
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Chlorobis(4-(trifluoromethyl)phenyl)phosphane

  • CAS No. 13685-24-0

  • Cat. No. CS-0213090
  • Purity≥98%
  • MDL No.MFCD04972304

*For research and further manufacturing use only, not for direct human use.

Chlorobis(4-(trifluoromethyl)phenyl)phosphane|CS-0213090

Structure of 13685-24-0

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General Information

  • CAS No. 13685-24-0
  • Cat. No. CS-0213090
  • Purity ≥98%
  • MDL No. MFCD04972304
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₄H₈ClF₆P
  • Molecular Weight 356.63
  • Synonym(s) Chlorobis[4-(Trifluoromethyl)Phenyl]Phosphine
  • SMILES C1=C(C=CC(=C1)P(C2=CC=C(C=C2)C(F)(F)F)Cl)C(F)(F)F

Description

6-Heptynoic acid is a reagent with an alkyne group and a carboxylic acid. The terminal carboxylic acid can form amide bond with primary amines (activation is needed). The alkyne can form triazole linkage with azide containing molecules via copper catalyzed reactions. Reagent grade, for research use only.

Synthesis

  • Route1
    • (Diethylamino)bis(4-trifluoromethylphenyl)phosphane|CS-0735489
      13685-91-1
    • ~%
    • Chlorobis(4-(trifluoromethyl)phenyl)phosphane|CS-0213090
      13685-24-0

    References

    • Journal of the American Chemical Society, , vol. 116, # 22 p. 9869 - 9882
  • Route2
    • null|null
      402-51-7
    • ~%
    • Chlorobis(4-(trifluoromethyl)phenyl)phosphane|CS-0213090
      13685-24-0

    References

    • Organic Letters, , vol. 6, # 25 p. 4675 - 4678
  • Route3

    References

    • Journal of the American Chemical Society, , vol. 116, # 22 p. 9869 - 9882

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3265
Class : 8
Packing Group : Ⅱ
Hazard Statements : H314-H318
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   5.3107
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   2

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