3-Bromo-5-fluoro-4-methylbenzaldehyde

Name: 3-Bromo-5-fluoro-4-methylbenzaldehyde
Brand: ChemScene
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CAS No. 1370411-47-4
Cat. No. CS-0147288
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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3-Bromo-5-fluoro-4-methylbenzaldehyde|CS-0147288

Structure of 1370411-47-4

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General Information

CAS No. 1370411-47-4
Cat. No. CS-0147288
Purity ≥98%
MDL No. None
Storage -20°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₆BrFO
Molecular Weight 217.04
Synonym(s) 5-Bromo-3-fluoro-4-methylbenzaldehyde
SMILES O=CC1=CC(F)=C(C)C(Br)=C1

Description

3-Bromo-5-fluoro-4-methylbenzaldehyde features a trifunctional aromatic core with bromo, fluoro, and methyl substituents positioned for orthogonal reactivity. The aldehyde group enables direct coupling in cross-coupling or condensation reactions. This electron-deficient aryl scaffold offers enhanced stability under standard conditions and facilitates selective functionalization in synthetic sequences.

Application

3-Bromo-5-fluoro-4-methylbenzaldehyde serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient construction of complex heterocyclic scaffolds. Its ortho-halogenated aryl core facilitates palladium-catalyzed cross-coupling reactions, while the aldehyde functionality supports reductive amination, Schiff base formation, and oxime derivatization. The methyl group provides a site for oxidation or functionalization, and the molecule exhibits good bench stability and compatibility with standard purification methods.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 17.07
LogP 2.70912
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-5-fluoro-4-methylbenzaldehyde

CAS No. 1370411-47-4

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