Ethyl 1-hydroxycyclopropane-1-carboxylate

Name: Ethyl 1-hydroxycyclopropane-1-carboxylate
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CAS No. 137682-89-4
Cat. No. CS-0049550
Purity≥97%
MDL No.MFCD01863257

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Ethyl 1-hydroxycyclopropane-1-carboxylate|CS-0049550

Structure of 137682-89-4

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Description

Ethyl 1-hydroxycyclopropane-1-carboxylate features a strained cyclopropyl ring bearing both hydroxyl and ester functionalities, enabling direct functionalization at the tertiary carbon. This bench-stable reagent integrates readily into synthetic sequences requiring stereoselective transformations or cyclopropanation-derived motifs.

Application

Ethyl 1-hydroxycyclopropane-1-carboxylate serves as a versatile building block in synthetic organic chemistry, enabling the construction of cyclopropyl-containing scaffolds via standard functional group interconversions. The pendant hydroxyl group offers direct access to esters, ethers, and ketones, while the strained cyclopropane ring enhances reactivity in ring-opening and cycloaddition processes. Its bench-stable nature and compatibility with common reaction conditions facilitate efficient synthesis of complex molecular architectures relevant to medicinal chemistry and natural product synthesis.

General Information

CAS No. 137682-89-4
Cat. No. CS-0049550
Purity ≥97%
MDL No. MFCD01863257
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₀O₃
Molecular Weight 130.14
Synonym(s) Ethyl 1-Hydroxycyclopropanecarboxylate, 90
SMILES CCOC(=O)C1(O)CC1

Computational Chemistry Data

TPSA 46.53
LogP 0.0744
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P260-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Fatty ring compounds Cyclopropane compounds

Key Words

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Ethyl 1-hydroxycyclopropane-1-carboxylate

CAS No. 137682-89-4

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