Tris(2,2'-bipyridine)ruthenium dichloride

Name: Tris(2,2'-bipyridine)ruthenium dichloride
Brand: ChemScene
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CAS No. 14323-06-9
Cat. No. CS-0082005
Molecule weight640.53
Purity≥98%
MDL No.MFCD00013224

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Tris(2,2'-bipyridine)ruthenium dichloride|CS-0082005

Structure of 14323-06-9

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General Information

CAS No. 14323-06-9
Cat. No. CS-0082005
Purity ≥98%
MDL No. MFCD00013224
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₀H₂₄Cl₂N₆Ru
Molecular Weight 640.53
Synonym(s) Tris(2,2'-bipyridine)ruthenium(II) dichloride
SMILES [N]1([Ru]234([N]5=CC=CC=C5C6=[N]4C=CC=C6)[N](C=CC=C7)=C7C8=CC=CC=[N]83)=C(C9=[N]2C=CC=C9)C=CC=C1

Description

Tris(2,2'-bipyridine)ruthenium dichloride delivers a robust, bench-stable platform for photochemical and electrochemical applications. The ruthenium center, coordinated by three bipyridine ligands, enables efficient visible-light absorption and long-lived excited states. This complex serves as a reliable redox probe and photocatalyst in solar energy conversion and molecular electronics.

Application

Tris(2,2′-bipyridine)ruthenium(II) dichloride serves as a well-established photosensitizer and redox catalyst in homogeneous transition metal chemistry. Its robust photophysical properties enable efficient triplet excitation transfer, facilitating applications in photocatalytic C–H functionalization, dye-sensitized solar cells, and electrochemically driven organic transformations. The complex exhibits excellent bench stability, predictable redox behavior, and compatibility with diverse reaction conditions, making it a reliable reagent for synthetic workflows requiring controlled single-electron transfer processes.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

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Tris(2,2'-bipyridine)ruthenium dichloride

CAS No. 14323-06-9

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