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CS-W001157 4
Total: USD 88.00

Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel

  • CAS No. 14647-23-5

  • Cat. No. CS-D1789
  • Molecule weight528.02
  • Purity≥98%
  • MDL No.MFCD00013313

*For research and further manufacturing use only, not for direct human use.

Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel|CS-D1789

Structure of 14647-23-5

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General Information

  • CAS No. 14647-23-5
  • Cat. No. CS-D1789
  • Purity ≥98%
  • MDL No. MFCD00013313
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₆H₂₄Cl₂NiP₂
  • Molecular Weight 528.02
  • Synonym(s) Dichloro[1,2-bis(diphenylphosphino)ethane]nickel; Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II); Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II)
  • SMILES Cl[Ni]1([P](C2=CC=CC=C2)(CC[P](C3=CC=CC=C3)1C4=CC=CC=C4)C5=CC=CC=C5)Cl

Description

Reactant involved in:Kumada catalyst-transfer polycondensationOxidation of carboranyl phosphine ligandsSynthesis of nickel-iron dithiolato hydridesUllmann reactions - homocoupling reactionsCo-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centersCatalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes

Synthesis

  • Route1
    • null|null
      19615-83-9
    • ~%
    • In-stock
      Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel|CS-D1789
      14647-23-5

    References

    • Ni: MVol.C2, 8.20, page 1073 - 1085
  • Route2
    • null|null
      14647-21-3
    • ~%
    • In-stock
      Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel|CS-D1789
      14647-23-5

    References

    • Ni: MVol.C2, 8.20, page 1073 - 1085
  • Route3
    • null|null
      19615-83-9
    • ~%
    • In-stock
      Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel|CS-D1789
      14647-23-5
    • In-stock
      Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel|CS-D1789
      14647-23-5

    References

    • Journal of the Chemical Society, , p. 3238 - 3241

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS08
Signal Word : Danger
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302+H312+H332-H315-H319-H334-H335-H350
Precautionary Statements : P261-P264-P270-P271-P280-P284-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   6.0933
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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