Methyl 2-bromo-5-hydroxybenzoate

Name: Methyl 2-bromo-5-hydroxybenzoate
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CAS No. 154607-00-8
Cat. No. CS-B1202
Purity≥96%
MDL No.MFCD10566797

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 2-bromo-5-hydroxybenzoate|CS-B1202

Structure of 154607-00-8

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Description

Methyl 2-bromo-5-hydroxybenzoate features a bromine atom at the ortho position and a hydroxyl group at the para position relative to the ester, creating a uniquely functionalized aromatic scaffold. This combination enables selective derivatization in synthetic routes requiring both electrophilic and nucleophilic handles. The compound exhibits good stability under standard bench conditions and integrates readily into multi-step sequences for bioactive molecule synthesis.

Application

Methyl 2-bromo-5-hydroxybenzoate serves as a versatile building block for functionalized aromatic scaffolds, enabling selective derivatization at the hydroxyl and ester groups. The bromo substituent facilitates palladium-catalyzed cross-coupling reactions, while the ortho-positioned hydroxyl allows for protection or direct transformation into ether or ester linkages. Its bench-stable nature and compatibility with standard synthetic protocols make it well-suited for medicinal chemistry and process development workflows.

General Information

CAS No. 154607-00-8
Cat. No. CS-B1202
Purity ≥96%
MDL No. MFCD10566797
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrO₃
Molecular Weight 231.04
Synonym(s) 2-Bromo-5-hydroxybenzoic acid methyl ester; Methyl 2-bromo-5-hydroxybenzenecarboxylate; Benzoic acid, 2-bromo-5-hydroxy-, methyl ester
SMILES O=C(OC)C1=CC(O)=CC=C1Br

Computational Chemistry Data

TPSA 46.53
LogP 1.9413
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 2-bromo-5-hydroxybenzoate

CAS No. 154607-00-8

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