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CS-W001157 4
Total: USD 88.00

Tris(triphenylphosphine)ruthenium(II) dichloride

  • CAS No. 15529-49-4

  • Cat. No. CS-0020064
  • Molecule weight958.85
  • Purity≥97%
  • MDL No.MFCD00013077

*For research and further manufacturing use only, not for direct human use.

Tris(triphenylphosphine)ruthenium(II) dichloride|CS-0020064

Structure of 15529-49-4

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General Information

  • CAS No. 15529-49-4
  • Cat. No. CS-0020064
  • Purity ≥97%
  • MDL No. MFCD00013077
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅₄H₄₅Cl₂P₃Ru
  • Molecular Weight 958.85
  • Synonym(s) Tris(triphenylphosphine)ruthenium dichloride; Tris(triphenylphosphine)ruthenium(II) dichloride; Tris(triphenylphosphine)ruthenium(II)chloride
  • SMILES Cl[Ru](Cl)[P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[3]

Description

Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize: Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group. 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation. Vinyl chloride monomer by hydrochlorination reaction of acetylene.RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.

Synthesis

  • Route1

    References

    • Vriends, Rob. C. J.; Koten, Gerard van; Vrieze, Kees Inorganica Chimica Acta, 1978 , vol. 26, p. L29 - L31
  • Route2
    • null|null
      15203-91-5
    • null|null
      603-35-0
    • ~96%
    • In-stock
      Tris(triphenylphosphine)ruthenium(II) dichloride|CS-0020064
      15529-49-4

    References

    • Ortiz-Frade, Luis A.; Ruiz-Ramirez, Lena; Gonzalez, Ignacio; Marin-Becerra, Armando; Alcarazo, Manuel; Alvarado-Rodriguez, Jose G.; Moreno-Esparza, Rafael Inorganic Chemistry, 2003 , vol. 42, # 6 p. 1825 - 1834
  • Route3

    References

    • Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 26, p. 1334 - 1336 Zhurnal Neorganicheskoi Khimii, , vol. 26, p. 2483 - 2486

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   0
  • LogP   5.1897
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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