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CS-W001157 4
Total: USD 88.00

Allyl phenyl carbonate,95%(stabilized with MEHQ)

  • CAS No. 16308-68-2

  • Cat. No. CS-0157981
  • Molecule weight178.18
  • Purity95%(stabilized with MEHQ)
  • MDL No.MFCD07784342

*For research and further manufacturing use only, not for direct human use.

Allyl phenyl carbonate,95%(stabilized with MEHQ)|CS-0157981

Structure of 16308-68-2

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General Information

  • CAS No. 16308-68-2
  • Cat. No. CS-0157981
  • Purity 95%(stabilized with MEHQ)
  • MDL No. MFCD07784342
  • Storage Store at room temperature, keep dry and cool
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₀O₃
  • Molecular Weight 178.18
  • Synonym(s) Carbonic Acid Allyl Phenyl Ester
  • SMILES C=CCOC(=O)OC1=CC=CC=C1

Description

Allyl phenyl carbonate, stabilized with MEHQ, offers reliable performance in synthetic transformations requiring mild cleavage conditions. This bench-stable reagent features a labile carbonate linkage that facilitates efficient deprotection under physiological or catalytic conditions. Its compatibility with sensitive functional groups enables selective modifications in complex molecular architectures.

Application

Allyl phenyl carbonate, 95% (stabilized with MEHQ) serves as a reliable allyl transfer reagent in synthetic organic chemistry. It facilitates mild, selective deprotection of allyl-protected alcohols and amines under palladium-catalyzed conditions. The stabilizing effect of MEHQ enhances shelf life and operational safety, while the compound exhibits excellent bench stability, compatibility with diverse functional groups, and ease of purification—making it well-suited for iterative synthesis workflows in medicinal chemistry and process development.

Synthesis

  • Route1
    • null|null
      2937-50-0
    • null|null
      108-95-2
    • ~85%
    • In-stock
      Allyl phenyl carbonate,95%(stabilized with MEHQ)|CS-0157981
      16308-68-2

    References

    • Dieskau, Andre P.; Plietker, Bernd Organic Letters, 2011 , vol. 13, # 20 p. 5544 - 5547
  • Route2
    • null|null
      107-18-6
    • null|null
      1885-14-9
    • ~99%
    • In-stock
      Allyl phenyl carbonate,95%(stabilized with MEHQ)|CS-0157981
      16308-68-2

    References

    • Pothukanuri, Srinivasu; Pianowski, Zbigniew; Winssinger, Nicolas European Journal of Organic Chemistry, 2008 , # 18 p. 3141 - 3148
  • Route3
    • In-stock
      Diphenyl carbonate|CS-0015889
      102-09-0
    • null|null
      107-18-6
    • ~%
    • In-stock
      Allyl phenyl carbonate,95%(stabilized with MEHQ)|CS-0157981
      16308-68-2

    References

    • Cazeneuve; Morel Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1898 , vol. 127, p. 112

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H317-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   35.53
  • LogP   2.388
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   3

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