Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate

Name: Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate
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CAS No. 170235-19-5
Cat. No. CS-B1159
Purity≥98%
MDL No.MFCD09878491

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Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate|CS-B1159

Structure of 170235-19-5

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Description

Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate features a brominated pyridine core with orthogonal functional groups enabling direct coupling in cross-coupling reactions. The hydroxyl moiety offers a site for derivatization, while the ester group facilitates selective transformations. This bench-stable compound integrates readily into complex heterocyclic scaffolds under standard conditions.

Application

Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate serves as a versatile building block in heterocyclic synthesis, enabling direct functionalization at the C5 hydroxyl and C6 bromide positions. The molecule exhibits bench stability and compatibility with palladium-catalyzed cross-coupling reactions, facilitating access to substituted pyridine scaffolds. Its dual reactive handles—electrophilic bromide and nucleophilically modifiable hydroxyl—support sequential transformations for medicinal chemistry applications.

General Information

CAS No. 170235-19-5
Cat. No. CS-B1159
Purity ≥98%
MDL No. MFCD09878491
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrNO₃
Molecular Weight 232.03
Synonym(s) 6-bromo-5-hydroxy-pyridine-2-carboxylic acid methyl ester
SMILES OC1=CC=C(C(OC)=O)N=C1Br

Computational Chemistry Data

TPSA 59.42
LogP 1.3363
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 6-bromo-5-hydroxy-2-pyridinecarboxylate

CAS No. 170235-19-5

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