4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine

Name: 4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 1762-42-1
Cat. No. CS-0085760
Purity≥98%
MDL No.MFCD06204732

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine|CS-0085760

Structure of 1762-42-1

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Description

4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine is a bidentate ligand featuring two ethoxycarbonyl groups at the 4-positions of the bipyridine backbone. This electron-deficient scaffold enhances metal coordination stability and facilitates modular assembly in transition metal complexes. The ester functionalities offer synthetic handles for derivatization, enabling tailored coordination environments in catalysis and materials applications.

Application

4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine serves as a versatile ligand in transition metal catalysis, enabling efficient coordination to palladium, ruthenium, and copper complexes. Its dual ester-functionalized bipyridine core offers enhanced solubility and stability in organic media, facilitating use in cross-coupling reactions and homogeneous catalytic processes. The ethoxycarbonyl groups provide orthogonal reactivity for downstream derivatization, supporting modular synthesis of functionalized heterocyclic scaffolds.

General Information

CAS No. 1762-42-1
Cat. No. CS-0085760
Purity ≥98%
MDL No. MFCD06204732
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₆H₁₆N₂O₄
Molecular Weight 300.31
Synonym(s) Diethyl [2,2'-bipyridine]-4,4'-dicarboxylate
SMILES O=C(OCC)C=1C=CN=C(C1)C=2N=CC=C(C2)C(=O)OCC

Computational Chemistry Data

TPSA 78.38
LogP 2.497
H_Acceptors 6
H_Donors 0
Rotatable_Bonds 5

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Catalysts and Ligands Ligands Pyridine Ligands Bipyridine Ligands

Material Science Electronic Materials Dye-Sensitized Solar Cell (DSSC) Materials Ligands

Material Science Material Building Blocks Ligands for Functional Metal Complexes Bipyridine Ligands, Terpyridine Ligands

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Catalysis Nitrogen-Donor Ligands Pyridine Ligands

Catalysis Nitrogen-Donor Ligands Bipyridine Ligands, Terpyridine Ligands

Key Words

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4,4'-Bis(ethoxycarbonyl)-2,2'-bipyridine

CAS No. 1762-42-1

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