(S)-1,1'-Bi-2,2'-naphthol

Name: (S)-1,1'-Bi-2,2'-naphthol
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 18531-99-2
Cat. No. CS-W020139
Purity≥97%
MDL No.MFCD00004068

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Structure of 18531-99-2

Size

Price

Quantity

* Please select Quantity before adding items.

General Information

CAS No. 18531-99-2
Cat. No. CS-W020139
Purity ≥97%
MDL No. MFCD00004068
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₀H₁₄O₂
Molecular Weight 286.33
Synonym(s) None
SMILES OC1=CC=C2C=CC=CC2=[C@]1[C@]3=C(O)C=CC4=CC=CC=C34

Description

(S)-BINOL ligand in combination with titanium(IV) isopropoxide, forms (S)-(-)-BINOL-Ti complex, which is an effective chiral catalyst for:asymmetric addition of alkynylzinc to unactivated ketonesenantioselective ring-opening reaction of meso-stilbene oxide and cyclohexene oxide with anilinesasymmetric aryl transfers from triaryl(tetrahydrofuran)aluminum reagents to a wide variety of ketonesIt can also react with zirconium(IV) isopropoxide isopropanol complex to form a chiral Lewis acid catalyst for the facile enantioselective allylation of aldehydes by allyltributyltin.

Synthesis

Route1
- In-stock
  
  135-19-3
- ~98%
- In-stock
  
  18531-99-2
References
- Takizawa, Shinobu; Rajesh, Doss; Katayama, Tomomi; Sasai, Hiroaki Synlett, 2009 , # 10 p. 1667 - 1669
Route2
- In-stock
  
  602-09-5
- ~96%
- In-stock
  
  18531-99-2
References
- Hu, Gang; Holmes, Daniel; Gendhar, Brina Fay; Wulff, William D. Journal of the American Chemical Society, 2009 , vol. 131, # 40 p. 14355 - 14364
Route3
- In-stock
  
  135-19-3
- ~0%
- In-stock
  
  18531-94-7
- In-stock
  
  18531-99-2
References
- Hon, Sang-Wen; Li, Chun-Hsin; Kuo, Jen-Huang; Barhate; Liu, Yi-Hung; Wang, Yu; Chen, Chien-Tien Organic Letters, 2001 , vol. 3, # 6 p. 869 - 872

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS06
Signal Word : Danger	UN#: 2811
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

TPSA 40.46
LogP 5.0712
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

Catalysts and Ligands Ligands Double Alcohol Ligands BINOL Ligands

Catalysis Organocatalysts Asymmetric Organocatalysts

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Privileged Ligands and Complexes

Key Words

(S)-1,1'-Bi-2,2'-naphthol sigma(S)-1,1'-Bi-2,2'-naphthol manufacturer(S)-1,1'-Bi-2,2'-naphthol price(S)-1,1'-Bi-2,2'-naphthol structure(S)-1,1'-Bi-2,2'-naphthol SDSbuy (S)-1,1'-Bi-2,2'-naphthol(S)-1,1'-Bi-2,2'-naphthol supplier(S)-1,1'-Bi-2,2'-naphthol uses(S)-1,1'-Bi-2,2'-naphthol molecular weightprice of (S)-1,1'-Bi-2,2'-naphthol(S)-1,1'-Bi-2,2'-naphthol chemical name formula of (S)-1,1'-Bi-2,2'-naphthol

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

(S)-1,1'-Bi-2,2'-naphthol

CAS No. 18531-99-2

Recommended Products

General Information

Description

Synthesis

References

References

References

Safety Information

Quality Control

Computational Chemistry Data

Similar Products

Other Classifications

Recently Viewed Products

Key Words