1-Bromo-3-(tert-butyl)-5-iodobenzene

Name: 1-Bromo-3-(tert-butyl)-5-iodobenzene
Brand: ChemScene
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CAS No. 186772-43-0
Cat. No. CS-0173618
Purity≥97%
MDL No.MFCD18089329

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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1-Bromo-3-(tert-butyl)-5-iodobenzene|CS-0173618

Structure of 186772-43-0

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Description

1-Bromo-3-(tert-butyl)-5-iodobenzene features a sterically shielded tert-butyl group flanked by bromo and iodo substituents, enabling selective cross-coupling reactions. This dual-halogenated arene integrates readily into palladium-catalyzed transformations, offering enhanced stability under standard reaction conditions.

Application

1-Bromo-3-(tert-butyl)-5-iodobenzene serves as a versatile biaryl building block for palladium-catalyzed cross-coupling reactions. The bromo and iodo substituents enable sequential functionalization, while the sterically hindered tert-butyl group enhances stability and facilitates purification. This compound functions reliably in Suzuki, Stille, and Negishi couplings, offering predictable reactivity and compatibility with diverse reaction conditions.

General Information

CAS No. 186772-43-0
Cat. No. CS-0173618
Purity ≥97%
MDL No. MFCD18089329
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₂BrI
Molecular Weight 339.01
Synonym(s) 3-Bromo-5-iodo-1-tert-butylbenzene
SMILES IC1=CC(C(C)(C)C)=CC(Br)=C1

Computational Chemistry Data

TPSA 0
LogP 4.3512
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P261-P280-P304+P340

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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1-Bromo-3-(tert-butyl)-5-iodobenzene

CAS No. 186772-43-0

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