Methyl 3-bromo-5-hydroxybenzoate

Name: Methyl 3-bromo-5-hydroxybenzoate
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CAS No. 192810-12-1
Cat. No. CS-0146143
Purity≥98%
MDL No.MFCD10566800

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Methyl 3-bromo-5-hydroxybenzoate|CS-0146143

Structure of 192810-12-1

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Description

Methyl 3-bromo-5-hydroxybenzoate features a bromine substituent at the meta position relative to the ester, paired with a para-hydroxyl group that enables downstream functionalization. This electron-deficient aromatic scaffold integrates readily into cross-coupling reactions and serves as a key intermediate in bioactive molecule synthesis under standard conditions.

Application

Methyl 3-bromo-5-hydroxybenzoate serves as a versatile synthetic intermediate for the construction of bioactive heterocycles and pharmaceutical scaffolds. The ortho-bromo and meta-hydroxy groups enable selective metal-catalyzed cross-coupling and directed functionalization, while the methyl ester supports orthogonal transformations. Bench-stable and readily purified by recrystallization, it facilitates efficient access to substituted aromatic systems in medicinal chemistry and process development workflows.

General Information

CAS No. 192810-12-1
Cat. No. CS-0146143
Purity ≥98%
MDL No. MFCD10566800
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrO₃
Molecular Weight 231.04
Synonym(s) METHYL 5-BROMO-3-HYDROXYBENZOATE
SMILES O=C(OC)C1=CC(O)=CC(Br)=C1

Computational Chemistry Data

TPSA 46.53
LogP 1.9413
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 3-bromo-5-hydroxybenzoate

CAS No. 192810-12-1

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