4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine

Name: 4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 209901-86-0
Cat. No. CS-0160983
Purity≥98%
MDL No.MFCD06796986

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine|CS-0160983

Structure of 209901-86-0

Size

Price

Quantity

* Please select Quantity before adding items.

General Information

CAS No. 209901-86-0
Cat. No. CS-0160983
Purity ≥98%
MDL No. MFCD06796986
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₁H₁₄FN₃
Molecular Weight 327.36
Synonym(s) 4-(4-Fluorophenyl)-2,6-dipyridin-2-ylpyridine
SMILES FC1=CC=C(C=C1)C2=CC(=NC(=C2)C3=NC=CC=C3)C4=NC=CC=C4

Description

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine is a fluorinated terpyridine derivative featuring a para-fluorophenyl group conjugated to the central pyridine ring. This electron-deficient ligand integrates robust metal-chelating sites with enhanced solubility and stability under standard conditions. The fluorophenyl moiety improves electronic tuning and facilitates coordination in transition metal complexes for catalysis and materials applications.

Application

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine serves as a versatile ligand scaffold in transition metal catalysis, enabling efficient coordination to late-stage metals such as Pd, Pt, and Ru. Its fluorinated aryl extension enhances electron-withdrawing character and improves solubility in organic media. The terpyridine core provides three nitrogen donor sites for robust chelation, facilitating catalyst design in cross-coupling and homogeneous catalysis. Bench-stable and readily purified by column chromatography, it functions effectively in standard synthetic workflows requiring modular ligand systems.

Synthesis

Route1
- 1122-62-9
- 459-57-4
- ~92%
- In-stock
  
  209901-86-0
References
- Tu, Shujiang; Jia, Runhong; Jiang, Bo; Zhang, Junyong; Zhang, Yan; Yao, Changsheng; Ji, Shunjun Tetrahedron, 2007 , vol. 63, # 2 p. 381 - 388

Safety Information

Download SDS

GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

TPSA 38.67
LogP 5.0117
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Key Words

209901-86-0 sigma209901-86-0 manufacturer209901-86-0 price209901-86-0 structure209901-86-0 SDSbuy 209901-86-0209901-86-0 supplier209901-86-0 uses209901-86-0 molecular weightprice of 209901-86-0209901-86-0 chemical name formula of 209901-86-0

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine

CAS No. 209901-86-0

Recommended Products