Ethyl (2-bromophenyl)acetate

Name: Ethyl (2-bromophenyl)acetate
Brand: ChemScene
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CAS No. 2178-24-7
Cat. No. CS-0151599
Purity≥97%
MDL No.MFCD00051921

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 2178-24-7

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Description

Ethyl (2-bromophenyl)acetate features a brominated phenyl ring positioned ortho to the acetate ester, enabling direct functionalization in cross-coupling reactions. This bench-stable reagent integrates seamlessly into synthetic sequences requiring aryl halide handles, offering predictable regiochemistry and compatibility with palladium-catalyzed transformations under standard conditions.

Application

Ethyl (2-bromophenyl)acetate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted phenylacetic acid derivatives and functionalized heterocycles. The ortho-bromo substituent facilitates palladium-catalyzed cross-coupling reactions, while the ester group supports selective transformations including reduction, hydrolysis, and nucleophilic substitution. Its bench-stable nature and compatibility with diverse reaction conditions make it a practical choice for medicinal chemistry and process development workflows.

General Information

CAS No. 2178-24-7
Cat. No. CS-0151599
Purity ≥97%
MDL No. MFCD00051921
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₁BrO₂
Molecular Weight 243.10
Synonym(s) Ethyl 2-(2-bromophenyl)acetate
SMILES CCOC(=O)CC1=CC=CC=C1Br

Computational Chemistry Data

TPSA 26.3
LogP 2.5547
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 3

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P302+P352-P304+P340

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Ethyl (2-bromophenyl)acetate

CAS No. 2178-24-7

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