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Structure of 23613-32-3
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1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
5,5-Dioxo-5H-dibenzo[b,d]thiophene-3,7-dicarboxylic acid serves as a robust, bench-stable building block for heterocyclic synthesis, enabling efficient access to complex polycyclic scaffolds via standard condensation and cyclization protocols. Its dual carboxylic acid functionality facilitates straightforward derivatization and conjugation, while the electron-deficient dibenzothiophene core exhibits excellent functional group tolerance and structural rigidity—ideal for medicinal chemistry campaigns requiring defined molecular architecture and synthetic reproducibility.
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GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Lot numbers can be found on the outside label of a product: