(4S,4'S)-1,1'-Bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole

Name: (4S,4'S)-1,1'-Bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole
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CAS No. 2374958-80-0
Cat. No. CS-0436606
Purity≥98%
MDL No.None

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(4S,4'S)-1,1'-Bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole|CS-0436606

Structure of 2374958-80-0

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Description

This chiral bis-imidazole features two tert-butyl-substituted aryl groups and diisopropyl moieties at the 4,4' positions, conferring exceptional steric shielding and solution stability. The (4S,4'S) stereochemistry ensures precise spatial control, enabling its use as a robust ligand in asymmetric catalysis and as a scaffold for functional materials requiring defined three-dimensional architecture under standard bench conditions.

Application

(4S,4'S)-1,1'-Bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole serves as a sterically hindered, bench-stable chiral ligand that enables asymmetric catalysis in transition-metal-mediated transformations. Its rigid biimidazole core and bulky substituents provide high enantioselectivity in palladium- and copper-catalyzed cross-coupling reactions, with excellent functional group tolerance and ease of purification.

General Information

CAS No. 2374958-80-0
Cat. No. CS-0436606
Purity ≥98%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₂H₄₆N₄
Molecular Weight 486.73
Synonym(s) None
SMILES CC(C)[C@@H]1CN(C2=CC=CC(C(C)(C)C)=C2)C(C3=N[C@@H](C(C)C)CN3C4=CC(C(C)(C)C)=CC=C4)=N1

Computational Chemistry Data

TPSA 31.2
LogP 7.468
H_Acceptors 4
H_Donors 0
Rotatable_Bonds 5

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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(4S,4'S)-1,1'-Bis(3-(tert-butyl)phenyl)-4,4'-diisopropyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole

CAS No. 2374958-80-0

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