Methyl 3-bromo-2-methoxybenzoate

Name: Methyl 3-bromo-2-methoxybenzoate
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CAS No. 260806-90-4
Cat. No. CS-0041494
Purity≥97%
MDL No.MFCD11042778

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FedEx Limited Quantities Ground	$0.00
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Methyl 3-bromo-2-methoxybenzoate|CS-0041494

Structure of 260806-90-4

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Description

Methyl 3-bromo-2-methoxybenzoate features a bromine atom at the meta position relative to the ester, paired with a methoxy group ortho to the carbonyl. This electron-deficient aromatic scaffold enables direct functionalization in cross-coupling reactions and serves as a key intermediate in synthesizing bioactive heterocycles and pharmaceuticals under standard conditions.

Application

Methyl 3-bromo-2-methoxybenzoate serves as a versatile building block for Suzuki-Miyaura and Stille coupling reactions, enabling the construction of biaryl and heteroaryl scaffolds under standard conditions. The bromine atom exhibits high reactivity in palladium-catalyzed cross-couplings, while the methoxy and ester groups provide orthogonal functionality for further derivatization. Its bench-stable nature and ease of purification make it well-suited for iterative synthesis workflows in medicinal chemistry and process development.

General Information

CAS No. 260806-90-4
Cat. No. CS-0041494
Purity ≥97%
MDL No. MFCD11042778
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₉BrO₃
Molecular Weight 245.07
Synonym(s) Benzoic acid, 3-bromo-2-methoxy-, methyl ester
SMILES COC(=O)C1=C(OC)C(Br)=CC=C1

Computational Chemistry Data

TPSA 35.53
LogP 2.2443
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Methyl 3-bromo-2-methoxybenzoate

CAS No. 260806-90-4

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