3-Chloro-2-fluorophenol

Name: 3-Chloro-2-fluorophenol
Brand: ChemScene
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CAS No. 2613-22-1
Cat. No. CS-W018221
Purity≥98%
MDL No.MFCD01631572

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 2613-22-1

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Description

3-Chloro-2-fluorophenol features a fluorine atom ortho to a hydroxyl group and a chlorine substituent at the adjacent position, creating a highly functionalized aromatic scaffold. This electron-deficient phenol integrates readily into synthetic sequences requiring directed ortho-metalation or coupling reactions. The molecule exhibits enhanced stability under standard bench conditions and delivers precise regiochemical control in complex heterocycle assembly.

Application

3-Chloro-2-fluorophenol serves as a versatile building block in medicinal chemistry, enabling direct functionalization at the ortho and meta positions relative to the phenolic hydroxyl group. Its halogenated aromatic framework supports palladium-catalyzed cross-coupling reactions and facilitates electrophilic substitution under controlled conditions. The compound exhibits good bench stability and is amenable to purification via standard techniques, making it well-suited for use in API intermediate synthesis and heterocyclic ring construction.

General Information

CAS No. 2613-22-1
Cat. No. CS-W018221
Purity ≥98%
MDL No. MFCD01631572
Storage RT, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₄ClFO
Molecular Weight 146.55
Synonym(s) Phenol, 3-chloro-2-fluoro-
SMILES OC1=CC=CC(Cl)=C1F

Computational Chemistry Data

TPSA 20.23
LogP 2.1847
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H412
Precautionary Statements : P264-P270-P273-P501

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Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Chloro-2-fluorophenol

CAS No. 2613-22-1

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