Methyl 6-bromopicolinate

Name: Methyl 6-bromopicolinate
Brand: ChemScene
Availability: InStock
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CAS No. 26218-75-7
Cat. No. CS-M1028
Purity≥98%
MDL No.MFCD06203934

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 26218-75-7

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Description

Methyl 6-bromopicolinate features a brominated pyridine ring with a methyl ester handle, enabling direct functionalization in cross-coupling and nucleophilic substitution reactions. This bench-stable derivative integrates readily into complex heterocyclic scaffolds under standard conditions.

Application

Methyl 6-bromopicolinate serves as a versatile building block in synthetic organic chemistry, enabling direct functionalization at the C-6 position via palladium-catalyzed cross-coupling reactions. Its bromine substituent exhibits high reactivity in Suzuki, Stille, and Negishi couplings, while the ester group provides orthogonal handle for further transformations. The compound demonstrates excellent bench stability and facilitates efficient purification, making it well-suited for iterative synthesis of heterocyclic scaffolds and pharmaceutical intermediates.

General Information

CAS No. 26218-75-7
Cat. No. CS-M1028
Purity ≥98%
MDL No. MFCD06203934
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrNO₂
Molecular Weight 216.03
Synonym(s) None
SMILES O=C(OC)C1=NC(Br)=CC=C1

Computational Chemistry Data

TPSA 39.19
LogP 1.6307
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

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Methyl 6-bromopicolinate

CAS No. 26218-75-7

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