Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)

Name: Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)
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CAS No. 27057-09-6
Cat. No. CS-0110820
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)|CS-0110820

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Application

Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II) serves as a well-defined, bench-stable precatalyst for cross-coupling reactions, enabling efficient C–C and C–heteroatom bond formation under mild conditions. Its ortho-methyl-substituted aryl ligand enhances stability and modulates reactivity, while the phosphine coordination facilitates oxidative addition and transmetalation steps. The complex demonstrates broad functional group tolerance and is particularly effective in Suzuki-Miyaura and Negishi coupling protocols, offering reliable performance in synthetic workflows requiring reproducible catalytic activity and straightforward handling.

General Information

CAS No. 27057-09-6
Cat. No. CS-0110820
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₃H₃₇ClNiP₂
Molecular Weight 709.85
Synonym(s) Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)
SMILES Cl[Ni]([P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)C7=C(C)C=CC=C7

Computational Chemistry Data

TPSA 0
LogP 8.21082
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 9

Safety Information

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GHS Pictogram :	GHS No : GHS07,GHS08
Signal Word : Danger	UN#: 3077
Class : 9	Packing Group : Ⅲ
Hazard Statements : H317-H350
Precautionary Statements : P280-P302+P352

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Bis(triphenylphosphino)(2-methylphenyl)chloronickel(II)

CAS No. 27057-09-6

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