2-Bromo-5-methoxytoluene

Name: 2-Bromo-5-methoxytoluene
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CAS No. 27060-75-9
Cat. No. CS-W001186
Purity≥95%
MDL No.MFCD00060687

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Description

2-Bromo-5-methoxytoluene features a methoxy group positioned ortho to the bromine, enhancing electronic effects for selective coupling reactions. This bench-stable aromatic compound integrates readily into cross-coupling protocols and serves as a key intermediate in pharmaceutical and agrochemical synthesis.

Application

2-Bromo-5-methoxytoluene serves as a versatile aryl building block for palladium-catalyzed cross-coupling reactions, enabling efficient construction of biaryl and heteroaryl architectures. Its bromine moiety exhibits high reactivity in Suzuki, Stille, and Negishi couplings, while the methoxy group provides moderate electron-donating character and orthogonal functionality for subsequent transformations. The compound demonstrates excellent bench stability, facilitating handling and purification in routine synthetic workflows.

General Information

CAS No. 27060-75-9
Cat. No. CS-W001186
Purity ≥95%
MDL No. MFCD00060687
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₉BrO
Molecular Weight 201.06
Synonym(s) Benzene, 1-bromo-4-methoxy-2-methyl-
SMILES COc1ccc(c(c1)C)Br

Computational Chemistry Data

TPSA 9.23
LogP 2.76612
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

Quality Control

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Other Classifications

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-5-methoxytoluene

CAS No. 27060-75-9

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