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CS-W001157 4
Total: USD 88.00

Dimethyl (diazomethyl)phosphonate

  • CAS No. 27491-70-9

  • Cat. No. CS-0197547
  • Purity≥97%
  • MDL No.MFCD16876592

*For research and further manufacturing use only, not for direct human use.

Dimethyl (diazomethyl)phosphonate|CS-0197547

Structure of 27491-70-9

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General Information

  • CAS No. 27491-70-9
  • Cat. No. CS-0197547
  • Purity ≥97%
  • MDL No. MFCD16876592
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃H₇N₂O₃P
  • Molecular Weight 150.07
  • Synonym(s) Seyferth-Gilbert Reagent
  • SMILES COP(=O)(C=[N+]=[N-])OC

Synthesis

  • Route1
    • Dimethyl ((1,3-dioxoisoindolin-2-yl)methyl)phosphonate|CS-0336041
      28447-26-9
    • ~46%
    • In-stock
      Dimethyl (diazomethyl)phosphonate|CS-0197547
      27491-70-9

    References

    • Nahrwold, Markus; Bogner, Tobias; Eissler, Stefan; Verma, Spart; Sewald, Norbert Organic Letters, 2010 , vol. 12, # 5 p. 1064 - 1067
  • Route2
    • null|null
      90965-06-3
    • ~91%
    • In-stock
      Dimethyl (diazomethyl)phosphonate|CS-0197547
      27491-70-9

    References

    • Ohira, Susumu Synthetic Communications, 1989 , vol. 19, # 3and4 p. 561 - 564
  • Route3
    • null|null
      2158-14-7
    • ~%
    • In-stock
      N-Acetylsulfanilamide|CS-0080221
      121-61-9
    • In-stock
      Dimethyl (diazomethyl)phosphonate|CS-0197547
      27491-70-9

    References

    • Brown, Dean G.; Velthuisen, Emil J.; Commerford, Jessica R.; Brisbois, Ronald G.; Hoye, Thomas R. Journal of Organic Chemistry, 1996 , vol. 61, # 7 p. 2540 - 2541

Safety Information

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GHS Pictogram : N/A
GHS No : N/A
Signal Word : N/A
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

Quality Control

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Computational Chemistry Data

  • TPSA   71.93
  • LogP   0.7304
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   3

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