1,4-Diazabicyclo[3.2.2]nonane

Name: 1,4-Diazabicyclo[3.2.2]nonane
Brand: ChemScene
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CAS No. 283-38-5
Cat. No. CS-W003863
Purity≥95%
MDL No.MFCD14581694

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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1,4-Diazabicyclo[3.2.2]nonane|CS-W003863

Structure of 283-38-5

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Description

1,4-Diazabicyclo[3.2.2]nonane is a rigid, electron-rich heterocycle featuring two tertiary amine sites in a constrained bicyclic framework. This structure imparts strong basicity and nucleophilicity, enabling efficient catalysis in amidation, esterification, and C–H activation reactions. The molecule exhibits excellent bench stability and solubility in common organic solvents, facilitating straightforward handling in synthetic workflows.

Application

1,4-Diazabicyclo[3.2.2]nonane serves as a versatile, bench-stable organic base in synthetic chemistry, enabling efficient deprotonation and facilitating key transformations such as Mannich reactions, Michael additions, and nucleophilic substitutions. Its rigid bicyclic structure imparts high basicity with minimal nucleophilicity, enhancing selectivity in complex molecule synthesis. Widely used in catalytic systems and as a building block for functionalized heterocycles, it functions effectively in both small-molecule drug discovery and process-scale applications.

General Information

CAS No. 283-38-5
Cat. No. CS-W003863
Purity ≥95%
MDL No. MFCD14581694
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₁₄N₂
Molecular Weight 126.20
Synonym(s) 1,4-Diazobicylco[3.2.2]nonane
SMILES C1NC2CCN(C1)CC2

Computational Chemistry Data

TPSA 15.27
LogP 0.054
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Building Blocks Skeleton Bridge Rings compounds Other bridge ring compounds

Key Words

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1,4-Diazabicyclo[3.2.2]nonane

CAS No. 283-38-5

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