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CS-W001157 4
Total: USD 88.00

Cyclopropyl(phenyl)methanone

  • CAS No. 3481-02-5

  • Cat. No. CS-W010990
  • Purity≥97%
  • MDL No.MFCD00001294

*For research and further manufacturing use only, not for direct human use.

Cyclopropyl(phenyl)methanone|CS-W010990

Structure of 3481-02-5

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General Information

  • CAS No. 3481-02-5
  • Cat. No. CS-W010990
  • Purity ≥97%
  • MDL No. MFCD00001294
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₀O
  • Molecular Weight 146.19
  • Synonym(s) Cyclopropyl phenyl ketone
  • SMILES O=C(C1CC1)C2=CC=CC=C2

Description

Cyclopropyl phenyl ketone was used to prepare -cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Synthesis

  • Route1
    • (Cyclopropylmethyl)Benzene|CS-0767755
      1667-00-1
    • ~75%
    • In-stock
      Cyclopropyl(phenyl)methanone|CS-W010990
      3481-02-5

    References

    • Tetrahedron Letters, , vol. 49, # 23 p. 3709 - 3712
  • Route2

    References

    • Angewandte Chemie - International Edition, , vol. 44, # 22 p. 3423 - 3426
  • Route3
    • null|null
      5500-21-0
    • In-stock
      Phenylboronic acid|CS-W001090
      98-80-6
    • ~85%
    • In-stock
      Cyclopropyl(phenyl)methanone|CS-W010990
      3481-02-5

    References

    • Synthesis (Germany), , vol. 45, # 16 art. no. SS-2013-F0255-OP, p. 2241 - 2244

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   2.2793
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   2

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